MSE 2016 - Full Program

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Keynote Lecture

Electromotive force study of Li-Sb alloys

Wednesday (28.09.2016)
14:45 - 15:15
Part of:

Lithium-antimony system attracted a lot of attention recently [1,2] due to its importance in development of novel liquid-metal batteries [3] and lithium-ion batteries [4], as well as incomplete thermodynamic data and discrepancies regarding phase diagram [5].

We used electromotive force method (emf) to study thermodynamic properties of Li-Sb alloys over broad range of concentrations (xLi = 0.1–0.7) and temperature (723–973 K). The Li-Bi alloy (xBi= 0.35) was used as a reference electrode, while eutectic mixtures KCl-LiCl and LiCl-LiF were used as liquid electrolytes. Attempts were made to use coulometric titration method combined with emf to study phase boundaries in the Li-Sb system.

In this presentation we would like to briefly report on features and design of our experimental method. Subsequently, experimental results will be shown and discussed.


[1] M.M. Kane, J.M. Newhouse, D.R. Sadoway, J. Electrochem. Soc. 162, A421-A425 (2015)

[2] S. Terlicka, A. Debski, P. Fima, J. Alloy Compd. 673, 272-277 (2016)

[3] K. Wang, K. Jiang, B. Chung et al., Nature 514, 348-350 (2014)

[4] W-J. Zhang, J. Power Sources, 196, 13-24 (2011)

[5] H. Okamoto, J. Phase Equilib., 17, 271 (1996)


Dr.-Ing. Przemyslaw Fima
Polish Academy of Sciences
Additional Authors:
  • Sylwia Terlicka
    Polish Academy of Sciences